Organosilicon linkers in metal organic frameworks: the tetrahedral tetrakis(4-tetrazolylphenyl)silane ligand.
نویسندگان
چکیده
Formal substitution of the central carbon by silicon within the tetrahedral tetrakis(4-tetrazolylphenyl)methane linker in a copper-based MOF is shown to uniquely influence the structure of the resultant MOF, affecting the orientation of the metal-based nodes and leading to an increase in unit-cell volume and solvent accessible void space.
منابع مشابه
Structure and charge control in metal-organic frameworks based on the tetrahedral ligand tetrakis(4-tetrazolylphenyl)methane.
Use of the tetrahedral ligand tetrakis(4-tetrazolylphenyl)methane enabled isolation of two three-dimensional metal-organic frameworks featuring 4,6- and 4,8-connected nets related to the structures of garnet and fluorite with the formulae Mn(6)(ttpm)(3)5 DMF3 H(2)O (1) and Cu[(Cu(4)Cl)(ttpm)(2)](2)CuCl(2)5 DMF11 H(2)O (2) (H(4)ttpm=tetrakis(4-tetrazolylphenyl)methane). The fluorite-type solid 2...
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عنوان ژورنال:
- Dalton transactions
دوره 42 38 شماره
صفحات -
تاریخ انتشار 2013